No, the dock does not have any duplication functionality, nor does it come with duplication software. It's just a dual-drive USB 3.0 dock for SATA drives.
Even with a bit-for-bit duplicator, unless you are simply replacing the drive in the same system, you will likely have to register or at least reactivate your software again. Software activation typically factors a number of things about the system - network MAC, CPU ID, etc.
Some software has the option to deactivate/unregister so you can reinstall it elsewhere. If your software is truly one-time install only licensed for the system it is initially installed on, you may not be able to use it on another machine even if you do manage to duplicate your drive.
Also, if you are migrating to a significantly different machine, your OS may not be able to even start up successfully on the new system.
For Office 2010 in particular, most times you can uninstall it on one system and install and activate it on another system, but if you do it too many times you'll have to call to get activated and may be denied depending on your license.