To use PCmover, simply install it on both your old and new Windows computers, and follow the easy-to-use wizard. When the transfer is complete, your new PC will have the personality and functionality of your old one. Because most transferred applications are installed ready-to-use on the new PC, there's usually no need to find old CDs or previously downloaded applications, serial numbers, or license codes. A single purchase of PCmover provides one license to migrate from one source to one destination computer - with as many attempts needed. Additional computers will require an additional license(s).
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I've used this software before (earlier versions) and it works like a charm. One caveat - make sure any conflicting software on the "new" PC is deleted and that you believe the recommendations. I would have saved myself several days of troubleshooting if I'd noticed a newer version of Office on the new PC and hadn't overwritten the recommendations against transferring the older version.